Despite their almost incomprehensibly（不可思议地） small size -- a diameter about one ten-thousandth the thickness of a human hair -- single-walled carbon nanotubes come in a plethora¹（过多，过剩） of different "species," each with its own structure and unique combination of electronic and optical properties. Characterizing the structure and properties of an individual carbon nanotube has involved a lot of guesswork -- until now. Researchers with the U.S. Department of Energy (DOE)'s Lawrence Berkeley National Laboratory (Berkeley Lab) and the University of California (UC) Berkeley have developed a technique that can be used to identify the structure of an individual carbon nanotube and characterize its electronic and optical properties in a functional² device.

 

"Using a novel high-contrast polarization-based optical microscopy（光学显微镜） set-up, we've demonstrated video-rate imaging and in-situ spectroscopy of individual carbon nanotubes on various substrates and in functional devices," says Feng Wang, a condensed matter physicist³ with Berkeley Lab's Materials Sciences Division. "For the first time, we can take images and spectra⁴ of individual nanotubes in a general environment, including on substrates or in functional devices, which should be a great tool for advancing nanotube technology."

 

Wang, who is also a professor with UC Berkeley's Physics Department, is the corresponding author of a paper describing this research in the journal Nature Nanotechnology. Co-authors are Kaihui Liu, Xiaoping Hong, Qin Zhou, Chenhao Jin, Jinghua Li, Weiwei Zhou, Jie Liu, Enge Wang and Alex Zettl.

 

A single-walled carbon nanotube can be metallic⁵ or semiconducting depending on its exact structure. Semiconducting nanotubes can have very different electronic bandgaps, resulting in wildly different electronic or optical properties.

 

"To fully⁶ understand field-effect devices or optoelectronic devices made from single-walled carbon nanotubes, it is critical to know what species of carbon nanotube is in the device," Wang says. "In the past, such information could not be obtained and researchers had to guess as to what was going on."

 

The physical structure and electronic properties of each individual species of single-walled carbon nanotubes are governed by chirality（偏光力）, meaning their structure has a distinct left/right orientation⁷ or "handedness," which cannot be superimposed on a mirror image. As a result, achieving chirality-controlled growth of carbon nanotubes and understanding the physics behind chirality-dependent devices are two of the biggest challenges in nanotube research.

 

"Polarization-based optical microscopy and spectroscopy techniques are well-suited for meeting these challenges, as polarized light is extremely sensitive to optical anisotropy in a system and has long been exploited to study chirality in molecules⁸ and crystals," Wang says. "However, the small signal and unavoidable environment background has made it difficult to use polarized optical microscopy to study single carbon nanotubes."

 

Difficulties arise from an apparent contradiction in polarization-based optical microscopy. For any optical microscope, a large numerical aperture⁹ (NA) objective is crucial for high-spatial¹⁰ resolution, but polarized light passing through a large NA objective becomes strongly depolarized. With their new technique, Wang and his colleagues were able to do what has not been done before and simultaneously¹¹ achieve both high polarization and high spatial resolution.

 

"The key to our success was the realization¹² that light illumination and light collection can be controlled separately," Wang says. "We used a large NA objective for light collection to obtain high spatial resolution, but were able to create an effectively small NA objective for illumination to maintain high polarization purity."

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