光脉冲能控制石墨烯的电气性能

Graphene, an ultrathin form of carbon with exceptional electrical, optical, and mechanical properties, has become a focus of research on a variety of potential uses. Now researchers at MIT have found a way to control how the material conducts electricity by using extremely short light pulses, which could enable its use as a broadband light detector¹. The new findings are published in the journal Physical Review Letters, in a paper by graduate student Alex Frenzel, Nuh Gedik, and three others.

 

The researchers found that by controlling the concentration of electrons in a graphene sheet, they could change the way the material responds to a short but intense light pulse. If the graphene sheet starts out with low electron concentration, the pulse increases the material's electrical conductivity. This behavior is similar to that of traditional semiconductors², such as silicon³ and germanium（锗）.

 

But if the graphene starts out with high electron concentration, the pulse decreases its conductivity -- the same way that a metal usually behaves. Therefore, by modulating⁴ graphene's electron concentration, the researchers found that they could effectively alter graphene's photoconductive properties from semiconductorlike to metallike.

 

The finding also explains the photoresponse of graphene reported previously⁵ by different research groups, which studied graphene samples with differing concentration of electrons. "We were able to tune⁶ the number of electrons in graphene, and get either response," Frenzel says.

 

To perform this study, the team deposited graphene on top of an insulating layer with a thin metallic⁷ film beneath it; by applying a voltage between graphene and the bottom electrode, the electron concentration of graphene could be tuned⁸. The researchers then illuminated⁹ graphene with a strong light pulse and measured the change of electrical conduction by assessing the transmission of a second, low-frequency light pulse.

 

In this case, the laser performs dual¹⁰ functions. "We use two different light pulses: one to modify the material, and one to measure the electrical conduction," Gedik says, adding that the pulses used to measure the conduction are much lower frequency than the pulses used to modify the material behavior. To accomplish this, the researchers developed a device that was transparent¹¹, Frenzel explains, to allow laser pulses to pass through it.

 

This all-optical method avoids the need for adding extra electrical contacts to the graphene. Gedik, the Lawrence C. and Sarah W. Biedenharn Associate Professor of Physics, says the measurement method that Frenzel implemented¹² is a "cool technique. Normally, to measure conductivity you have to put leads on it," he says. This approach, by contrast, "has no contact at all."

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