太阳能电池板可将二氧化碳转化为甲酸

Research to curb¹ global warming caused by rising levels of atmospheric² greenhouse gases, such as carbon dioxide, usually involves three areas: Developing alternative energy sources, capturing and storing greenhouse gases, and repurposing（再利用） excess greenhouse gases. Drawing on two of these approaches, researchers in the laboratory of Andrew Bocarsly, a Princeton professor of chemistry, collaborated³ with start-up company Liquid Light Inc. of Monmouth Junction⁴, N.J. to devise an efficient method for harnessing sunlight to convert carbon dioxide into a potential alternative fuel known as formic acid（甲酸，蚁酸）. The study was published June 13 in the Journal of CO2 Utilization⁵. The transformation⁶ from carbon dioxide and water to formic acid was powered by a commercial solar panel generously provided by the energy company PSE&G that can be found atop electric poles across the state. The process takes place inside an electrochemical cell, which consists of metal plates the size of rectangular（矩形的） lunch-boxes that enclose liquid-carrying channels.

 

To maximize the efficiency of the system, the amount of power produced by the solar panel must match the amount of power the electrochemical cell can handle, said Bocarsly. This optimization⁷ process is called impedance matching（阻抗匹配）. By stacking three electrochemical cells together, the research team was able to reach almost 2 percent energy efficiency, which is twice the efficiency of natural photosynthesis⁸. It is also the best energy efficiency reported to date using a human-made device.

 

A number of energy companies are interested in storing solar energy as formic acid in fuel cells. Additionally, formate（甲酸盐） salt -- readily made from formic acid -- is the preferred de-icing agent on airplane runways because it is less corrosive⁹ to planes and safer for the environment than chloride salts. With increased availability, formate salts could supplant¹⁰（代替） more harmful salts in widespread use.

 

Using waste carbon dioxide and easily obtained machined parts, this approach offers a promising¹¹ route to a renewable fuel, Bocarsly said.

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